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Methanol CAS#67-56-1

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Chemical Name:Methanol
CAS No.67-56-1
Molecular Formula:CH4O
Molecular weight: 32.04
Sample: Available
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PRODUCT DESCRIPTION

Products Description of Methanol CAS#67-56-1

Methanol, also known as "wood alcohol", is an organic compound and the simplest saturated monohydric alcohol. It is a colorless, transparent, flammable, volatile toxic liquid. Ingestion of 5 to 10 ml can cause blindness, and drinking a large amount can lead to death. Methanol is non-corrosive to metals at room temperature (except lead and aluminum) and has a slight alcohol smell. Relative density 0.792 (20/4℃), melting point -97.8℃, boiling point 64.5℃, flash point 12.22℃, autoignition point 463.89℃, vapor density 1.11, vapor pressure 13.33KPa (100mmHg21.2℃), vapor and air mixture explosion limit 6 to 36.5% (volume ratio), miscible with water, ethanol, ether, benzene, ketones, halogenated hydrocarbons and many other organic solvents. It is usually used as a solvent, antifreeze, fuel or neutralizer.


Methanol Chemical Properties

Melting point

-98 °C(lit.)

Boiling point

65.4 °C(lit.)

density

0.791 g/mL at 25 °C

vapor density

1.11 (vs air)

vapor pressure

410 mm Hg ( 50 °C)

refractive index

n20/D 1.329(lit.)

Fp

52 °F

storage temp.

2-8°C

solubility

benzene: miscible(lit.)

pka

15.2(at 25℃)

form

Liquid Free From Particulates

color

<10(APHA)

Specific Gravity

0.793 (20/20℃)

Relative polarity

0.762

Odor

Faint alcohol odor detectable at 4 to 6000 ppm (mean = 160 ppm)

explosive limit

5.5-44%(V)

Odor Threshold

33ppm

Water Solubility

miscible

λmax

λ: 210 nm Amax: 0.50λ: 220 nm Amax: 0.30λ: 230 nm Amax: 0.15λ: 235 nm Amax: 0.10λ: 240 nm Amax: 0.05λ: 260 nm Amax: 0.01λ: 400 nm Amax: 0.01

Merck

14,5957

BRN

1098229

Henry's Law Constant

4.99 at 25 °C (headspace-GC, Gupta et al., 2000)

Exposure limits

TLV-TWA (200 ppm) (ACGIH), 260mg/m3, 1040mg/m3 (800 ppm) 15minutes (NIOSH); STEL 310mg/m3 (250 ppm); IDLH 25,000 ppm (NIOSH).

Dielectric constant

33.6(20℃)

LogP

-0.770

CAS DataBase Reference

67-56-1(CAS DataBase Reference)

NIST Chemistry Reference

Methyl alcohol(67-56-1)

EPA Substance Registry System

Methanol (67-56-1)

Safety Information

Hazard Codes

Xn,T,F

Risk Statements

10-20/21/22-68/20/21/22-39/23/24/25-23/24/25-11-40-36-36/38-23/25

Safety Statements

36/37-7-45-16-24/25-23-24-26

RIDADR

UN 1170 3/PG 2

WGK Germany

1

RTECS

PC1400000

F

3-10

Autoignition Temperature

385 °C

TSCA

Yes

HS Code

2905 11 00

HazardClass

3

PackingGroup

II

Hazardous Substances Data

67-56-1(Hazardous Substances Data)

Toxicity

LD50 oral (rat)5628 mg/kgLD50 skin (rabbit)15,840 mg/kgLC50 inhal (rat)>145,000 ppm (1 h)PEL (OSHA)200 ppm (260 mg/m3)TLV-TWA (ACGIH)200 ppm (260 mg/m3)—skinSTEL (ACGIH)250 ppm (328 mg/m3)

IDLA

6,000 ppm


Product Application of  Methanol CAS#67-56-1

Methanol has a wide range of uses and is a basic organic chemical raw material and high-quality fuel. It is mainly used in the fields of fine chemicals and plastics to produce a variety of organic products such as formaldehyde, acetic acid, methyl chloride, methylamine, dimethyl sulfate, etc. It is also one of the important raw materials for pesticides and medicines. Methanol can be used as a new type of clean fuel after deep processing, and can also be added to gasoline for combustion. Methanol oxidation to formaldehyde Methanol is directly oxidized to formaldehyde in the presence of high temperature, pumice silver, catalyst or other solid catalyst. At present, more than 40% of methanol at home and abroad is used to produce formaldehyde, and then synthesize resins, plastics and other chemical raw materials. Polyoxymethylene is an engineering plastic with excellent performance and its uses are very wide. Formaldehyde is also used to produce nearly 100 downstream products such as butanediol and hexamethylenetetramine. Methanol ammonia to produce methylamine Methanol and ammonia are mixed in a certain proportion, and synthesized at 370~420℃ and 5.0~20.0MPa pressure with activated alumina as a catalyst to produce a mixture of monomethylamine, dimethylamine and trimethylamine, and then distilled to obtain monomethylamine, dimethylamine or trimethylamine products. Monomethylamine, dimethylamine and trimethylamine are used in pesticides, medicines, dyes or as organic raw material intermediates. Methanol can be dehydrated to produce dimethyl ether in the presence of metal silicon aluminum catalyst or ZSM-5 molecular sieve. Methanol is dehydrogenated to produce methyl formate. Methyl formate is a raw material for organic synthesis and can be used to make formamide, dimethylformamide, etc. Formamide is a raw material for medicine, fragrances, and dyes. It can also be used as a paper treatment agent, a softener in the fiber industry, and a polar solvent for organic synthesis. Dimethylformamide is an important organic chemical raw material and an excellent solvent. It can be used as a gas absorbent, pesticide, polyvinyl chloride synthetic leather, polyacrylonitrile spinning, butadiene extraction, etc.



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